Synthesis, characterization and anti-fouling properties of poly[vinylidene fluoride]-incorporated SiO2, TiO2, ZrO2 nanoparticle-LiCl pore former ultrafiltration membranes

Nita Aryanti; Aininu Nafiunisa; Alifia Rizki Adina; Tutuk Djoko Kusworo

doi:10.1016/j.cscee.2024.100664

Synthesis, characterization and anti-fouling properties of poly[vinylidene fluoride]-incorporated SiO₂, TiO₂, ZrO₂ nanoparticle-LiCl pore former ultrafiltration membranes

Nita Aryanti, Aininu Nafiunisa, Alifia Rizki Adina, Tutuk Djoko Kusworo

Department of Chemical Engineering

Research output: Contribution to journal › Article › peer-review

7 Citations (Scopus)

Abstract

Poly(vinylidene fluoride) (PVDF) was modified with SiO₂ (P–Si), TiO₂ (P–Ti), and ZrO₂ (P–Zr) nanoparticles, alongside LiCl. The modification aimed to enhance hydrophilicity, influence membrane porosity, and improve anti-fouling properties. Increased hydrophilicity was confirmed with reduction of contact angle from 89.8° to 64° for P–Zr membrane. Highest porosity of 81.986, highest water permeability (112.64 L/m².h) and FRR of 96.9% were achieved for P–Zr membrane. However, the P–Si exhibited the highest BOD rejection (99.76%), and P–Zr displayed the highest TOC rejection (96%). Overall, modification with ZrO₂–LiCl offering superior performance. These findings are significant for advancing UF membrane anti-fouling in oily wastewater treatment.

Original language	English
Article number	100664
Journal	Case Studies in Chemical and Environmental Engineering
Volume	9
DOIs	https://doi.org/10.1016/j.cscee.2024.100664
Publication status	Published - Jun 2024

Keywords

Hydrophilic
Membrane technology
Oily waste water
Separation

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

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10.1016/j.cscee.2024.100664

Cite this

@article{4949308d92ae4ff0924572c868c97525,

title = "Synthesis, characterization and anti-fouling properties of poly[vinylidene fluoride]-incorporated SiO2, TiO2, ZrO2 nanoparticle-LiCl pore former ultrafiltration membranes",

abstract = "Poly(vinylidene fluoride) (PVDF) was modified with SiO2 (P–Si), TiO2 (P–Ti), and ZrO2 (P–Zr) nanoparticles, alongside LiCl. The modification aimed to enhance hydrophilicity, influence membrane porosity, and improve anti-fouling properties. Increased hydrophilicity was confirmed with reduction of contact angle from 89.8° to 64° for P–Zr membrane. Highest porosity of 81.986, highest water permeability (112.64 L/m2.h) and FRR of 96.9\% were achieved for P–Zr membrane. However, the P–Si exhibited the highest BOD rejection (99.76\%), and P–Zr displayed the highest TOC rejection (96\%). Overall, modification with ZrO2–LiCl offering superior performance. These findings are significant for advancing UF membrane anti-fouling in oily wastewater treatment.",

keywords = "Hydrophilic, Membrane technology, Oily waste water, Separation",

author = "Nita Aryanti and Aininu Nafiunisa and Adina, \{Alifia Rizki\} and Kusworo, \{Tutuk Djoko\}",

note = "Publisher Copyright: {\textcopyright} 2024 The Authors",

year = "2024",

month = jun,

doi = "10.1016/j.cscee.2024.100664",

language = "English",

volume = "9",

journal = "Case Studies in Chemical and Environmental Engineering",

issn = "2666-0164",

publisher = "Elsevier Ltd",

}

Synthesis, characterization and anti-fouling properties of poly[vinylidene fluoride]-incorporated SiO₂, TiO₂, ZrO₂ nanoparticle-LiCl pore former ultrafiltration membranes. / Aryanti, Nita; Nafiunisa, Aininu; Adina, Alifia Rizki et al.
In: Case Studies in Chemical and Environmental Engineering, Vol. 9, 100664, 06.2024.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Synthesis, characterization and anti-fouling properties of poly[vinylidene fluoride]-incorporated SiO2, TiO2, ZrO2 nanoparticle-LiCl pore former ultrafiltration membranes

AU - Aryanti, Nita

AU - Nafiunisa, Aininu

AU - Adina, Alifia Rizki

AU - Kusworo, Tutuk Djoko

PY - 2024/6

Y1 - 2024/6

N2 - Poly(vinylidene fluoride) (PVDF) was modified with SiO2 (P–Si), TiO2 (P–Ti), and ZrO2 (P–Zr) nanoparticles, alongside LiCl. The modification aimed to enhance hydrophilicity, influence membrane porosity, and improve anti-fouling properties. Increased hydrophilicity was confirmed with reduction of contact angle from 89.8° to 64° for P–Zr membrane. Highest porosity of 81.986, highest water permeability (112.64 L/m2.h) and FRR of 96.9% were achieved for P–Zr membrane. However, the P–Si exhibited the highest BOD rejection (99.76%), and P–Zr displayed the highest TOC rejection (96%). Overall, modification with ZrO2–LiCl offering superior performance. These findings are significant for advancing UF membrane anti-fouling in oily wastewater treatment.

AB - Poly(vinylidene fluoride) (PVDF) was modified with SiO2 (P–Si), TiO2 (P–Ti), and ZrO2 (P–Zr) nanoparticles, alongside LiCl. The modification aimed to enhance hydrophilicity, influence membrane porosity, and improve anti-fouling properties. Increased hydrophilicity was confirmed with reduction of contact angle from 89.8° to 64° for P–Zr membrane. Highest porosity of 81.986, highest water permeability (112.64 L/m2.h) and FRR of 96.9% were achieved for P–Zr membrane. However, the P–Si exhibited the highest BOD rejection (99.76%), and P–Zr displayed the highest TOC rejection (96%). Overall, modification with ZrO2–LiCl offering superior performance. These findings are significant for advancing UF membrane anti-fouling in oily wastewater treatment.

KW - Hydrophilic

KW - Membrane technology

KW - Oily waste water

KW - Separation

UR - https://www.scopus.com/pages/publications/85186095142

U2 - 10.1016/j.cscee.2024.100664

DO - 10.1016/j.cscee.2024.100664

M3 - Article

AN - SCOPUS:85186095142

SN - 2666-0164

VL - 9

JO - Case Studies in Chemical and Environmental Engineering

JF - Case Studies in Chemical and Environmental Engineering

M1 - 100664

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